Catalytic Pyrolysis of Hydrochar by Calcined Eggshells for Bioenergy Production: Improved Thermo-Kinetic Studies and Reduced Pollutant Emissions

نویسندگان

چکیده

Bioenergy production from hydrochar via catalytic thermal conversion is of increasing importance to easing the energy shortage. The pyrolysis characteristics derived sawdust (HSD) with calcined eggshell (CES) were investigated by thermogravimetric–Fourier transform infrared spectroscopy–mass spectrometry (TG-FTIR-MS) method. Kinetic and thermodynamic parameters determined two iso-conversional model-free methods, namely, Kissinger–Akahira–Sunose (KAS) Flynn–Wall–Ozawa (FWO). results demonstrated that HSD exhibited a high fuel quality, elevated carbon content (54.03%) an increased calorific value (21.65 MJ Kg−1). CES significantly enhanced behavior promoting secondary cracking organic vapors under synergistic effect CaO mineral elements. Compared non-catalytic pyrolysis, residual mass average activation HSD-CES decreased 29.61% 14.10%, respectively, gaseous products H2 CO 26.14% 22.94%, respectively. Furthermore, participation effectively suppressed emission pollutants in process, 27.13% reduction CH4, 22.76% HCN, 20.28% NH3. This study provides valuable guidance on potential use for renewable production.

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ژورنال

عنوان ژورنال: Catalysts

سال: 2023

ISSN: ['2073-4344']

DOI: https://doi.org/10.3390/catal13091297